Converting rubber seed oil into hydrocarbon fuels via supported Pd-catalyst
DOI:
https://doi.org/10.25165/ijabe.v10i6.2742Keywords:
rubber tree seed oil, catalytic cracking, Pd based catalyst, hydrocarbon fuels, biofuel, renewable energyAbstract
The one-step hydrotreatment of rubber seed oil to produce hydrocarbon fuels has been carried out via supported Pd-catalyst, and analyzed emphatically some elements affected catalytic cracking process, for example, temperature, hydrogen partial pressure and dosage of catalyst, etc. Through experimental research, the author found out the appropriate catalytic cracking conditions as follows: 310°C of reaction temperature, 2 MPa of hydrogen partial pressure, 15 of the ratio of oil to catalyst (m(oil)/m(catalyst)), 100 r/min of stirring speed. Under these conditions, effective component of hydrocarbon fuels in the converted oil accounts for 99.49%, and the proportion of C8-C16 can reach as high as 79.61%. The converted oil was similar to petroleum-based oil in chemical composition, and can be used for future the aviation biofuels development as the source of raw material because it contains a large amount of hydrocarbon in the range of C8-C16. Keywords: rubber tree seed oil, catalytic cracking, Pd based catalyst, hydrocarbon fuels, biofuel, renewable energy DOI: 10.25165/j.ijabe.20171006.2742 Citation: Chen Y B, Hao Y J, Zhao Y Y, Zhou L M, Yang S P, Gao Y N, et al. Converting rubber seed oil into hydrocarbon fuels via supported Pd-catalyst. Int J Agric & Biol Eng, 2017; 10(6): 201–209.References
Wang D J, Liu H Y, Liu Y X, He C H, Liu C G. Progress in the study of bio fuels hydrogenation catalysts. Pet. Technol., 2012; 41(10): 1214–1219.
Gao J S, Xu C M, He J, Duan X, He M Y. Development and strategy research of chemical engineering discipline. Sci. China Chem., 2014; 44(9): 1385–1393.
He M Y, Li G H, Li H Q. About Yunnan rubber seed oil with the development present situation and the thinking. Tropic Agric. Sci. & Technol., 2010; 33(4): 36–43.
Wang X L, Zhan L. The rubber seed oil refining research. China Oil and Fat, 2000; 25(4): 10–11.
Ramadhas A S, Jayaraj S, Muraleedharan C. Biodiesel production from high FFA rubber seed oil. Fuel, 2005; 84(4): 335–340.
Geo V E, Nagarajan G, Kamalakannan J, Nagalingam B. Experimental investigations to study the characteristics of rubber-seed-oil-fueled diesel engine supplemented with diethyl ether. Energy Fuels, 2009; 23(1): 533–538.
Li C Z, Li P W, Xiao Z H, Chen J Z, Zhang L B. Woody biodiesel raw materials research and development in our country present situation and the industrialization prospects. J. of China Agric. Uni., 2012; 17(6): 165–170.
Li L, Quan K J, Xu J M, Liu F S, Liu S W, Yu S T, et al. Liquid hydrocarbon fuels from catalytic cracking of rubber seed oil using USY as catalyst. Fuel, 2014; 123(1): 189–193.
James A, Yuan W, Boyette M D, Wang D, Kumar A.. In-chamber thermocatalytic tar cracking and syngas reforming using char-supported NiO catalyst in an updraft biomass gasifier. Int. J. Agric. & Biol. Eng., 2014; 7(6): 91–96.
Zhang H, Zhang K, Zhou X H, Hu J J, Jing Y Y, Liu S Y. Thermal properties of biomass tar at rapid heating rates. Int. J. Agric. & Biol. Eng., 2014; 7(2): 101–107.
Xie Z K, Liu Z C, Wang Y D. Technology innovation and prospect of petroleum and chemical industry based on resource and environment. Sci. China Chem., 2014, 44(9): 1394–1403.
Yee K F, Wu J C S, Lee K T. A green catalyst for biodiesel production from jatropha oil: Optimization study. Biomass & Bioenergy, 2011; 35(5): 1739–1746.
Na J, Yi B E, Kim J N, Yi K B, Park S, Park J, et al. Hydrocarbon production from decarboxylation of fatty acid without hydrogen. Catal. Today, 2010; 156(1-2): 44–48.
Tian H, Li C Y, Yang C H, Shan H H. Alternative processing technology for converting vegetable oils and animal fats to clean fuels and light olefins. Chinese J. of Chem. Eng., 2008; 16(3): 394–400.
Demirbas A. Competitive liquid biofuels from biomass. Appl. Eneegy, 2011; 88(1): 17–28.
Wang Y P, Zhai Y, Zhang J L, Li W, Han Z T. Research progress of biodiesel preparation. Chem. Indu. and Eng. Prog., 2003; 22(1): 8-12.
Han W, Huang F H, Yang M, Liu C S, Huang Q D. Research progress of biological diesel low temperature fluidity and improved method. Chem. Indu. and Eng. Prog., 2007; 26(10): 1395–1399.
Santillan-Jimenez E, Morgan T, Lacny J, Mohapatra S, Crocker M. Catalytic deoxygenation of triglycerides and fatty acids to hydrocarbons over carbon-supported nickel. Fuel, 2013; 103(1): 1010–1017.
Morgan T, Santillan-Jimenez E, Harman-Ware A E, Ji Y Y, Grubb D, Crocker M. Catalytic deoxygenation of triglycerides to hydrocarbons over supported nickel catalysts. Chem. Eng. J., 2012; 189(2): 346–355.
Wang C, Thapaliya N, Campos A, Stikeleather L F, Roberts W L. Hydrocarbon fuels from vegetable oils via hydrolysis and thermo-catalytic decarboxylation. Fuel, 2012; 95(1): 622–629.
Immer J G, Jason Kelly M, Henry Lamb H. Catalytic reaction pathways in liquid-phase deoxygenation of C18 free fatty acids. Appl. Catal. A Gen., 2010; 375(1): 134–139.
Kubičková I, Snåre M, Eränen K, Mäki-Arvela P, Murzin D Y. Hydrocarbons for diesel fuel via decarboxylation of vegetable oils. Catal. Today, 2005; 106(1): 197–200.
Kubičková I, Kubička D. Utilization of triglycerides and related feedstocks for production of clean hydrocarbon fuels and petrochemicals: A review. Waste & Biomass Valorization, 2010; 1(3): 293–308(16).
Sun P P. Research of hydrocarbon production of vegetable oil and fat. Yunnan, Yunnan Normal University, 2014. (in Chinese)
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